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GHS hazard statement

H224: Extremely flammable liquid and vapor

  • H224
  • Physical hazards
  • Danger

H224 means “Extremely flammable liquid and vapor”. It is a GHS hazard statement for Flammable liquids (Category 1), shown with GHS02 under the signal word “Danger”.

Hazard class and category

Hazard classCategoryPictogramSignal wordUN transport class
Flammable liquidsCategory 1
GHS pictogram GHS02: Flame
DangerClass 3

What H224 means

Flammable liquids are liquids with a flash point of not more than 93 °C. The GHS sorts them into four categories by flash point and initial boiling point, with Category 1 the most hazardous.

The liquid gives off vapor that can ignite with air near a spark, flame or hot surface. Vapors are usually heavier than air and can travel along floors to a distant ignition source. The lower the flash point, the more easily the liquid ignites.

What to do

Keep away from heat, sparks, open flames and hot surfaces. Keep containers closed and grounded or bonded when transferring, use explosion-proof equipment, store in a cool well-ventilated place, and use the extinguishing media named on the SDS.

This is general guidance for the hazard class. The safety data sheet for your product always takes precedence.

Precautionary statements for H224

The GHS lists these precautionary statements for this hazard. Which ones appear on a label depends on the supplier's classification.

CodeStatement
P210Keep away from heat, hot surface, sparks, open flames and other ignition sources. No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof [electrical/ventilating/lighting/.../] equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P280Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P303+P361+P353IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P370+P378In case of fire: Use ... to extinguish.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to ...

Chemicals carrying H224

2 chemicals in our database. Classification comes from each chemical's primary GHS source, so a supplier's SDS may differ.

H224 frequently asked questions

What does H224 mean?

H224 means "Extremely flammable liquid and vapor". It is a GHS hazard statement in the physical hazards group, covering Flammable liquids (Category 1).

Which pictogram goes with H224?

H224 is shown with GHS02 (Flame).

What signal word goes with H224?

The signal word for H224 is "Danger".

Which precautionary statements go with H224?

The GHS data lists 11 precautionary statements for H224, including P210, P233, P240, P241, P242. They cover prevention, response, storage and disposal. The full list is on this page.

Hazard statements describe the hazard of a classified substance or mixture. The classification of a specific product can differ, so use the supplier's SDS.

https://pubchem.ncbi.nlm.nih.gov/ghs/ghscode_10.txt (UN GHS Revision 10, retrieved 2026-10-12)