Safety data summary
Anthracene
- CAS 120-12-7
- C14H10
- EC 204-371-1
- Danger
Anthracene (CAS 120-12-7) is a chemical substance with the molecular formula C14H10 and a molecular weight of 178.23 g/mol. Based on GHS classifications notified to ECHA, it carries the signal word “Danger” and is classified as a known or suspected carcinogen, an irritant, and hazardous to aquatic life. Its label shows the Exclamation Mark, Health Hazard, and Environment pictograms. Key hazard statements include H315 (causes skin irritation), H319 (causes serious eye irritation), and H350 (may cause cancer). The OSHA permissible exposure limit (PEL) is 0.2 mg/m³ as Coal tar pitch volatiles (benzene soluble fraction).
Hazards at a glance
- H315Causes skin irritation · 21.1% of notifications
- H319Causes serious eye irritation · 97.7% of notifications
- H350May cause cancer · 18.5% of notifications
- H400Very toxic to aquatic life · 21.1% of notifications
- H410Very toxic to aquatic life with long lasting effects · 22.2% of notifications
European Chemicals Agency (ECHA) — aggregated from 573 company reports
1Identification
- Name
- Anthracene
- IUPAC name
- anthracene
- CAS number
- 120-12-7
- EC number
- 204-371-1
- Molecular formula
- C14H10
- Molecular weight
- 178.23 g/mol
- InChIKey
- MWPLVEDNUUSJAV-UHFFFAOYSA-N
- SMILES
- C1=CC=C2C=C3C=CC=CC3=CC2=C1
- PubChem CID
- 8418
- Synonyms
- Paranaphthalene, Anthracin, Tetra Olive N2G, Anthracen, p-Naphthalene, Sterilite hop defoliant, RefChem:6382, Anthracen [German], Anthraxcene, Anthrazen, Acen, WLN: L C666J, Anthracene, pure, C14315
Recommended uses
- Used to make dyestuffs (anthraquinone and alizarin dyes); Also used to make synthetic fibers and plastics and in semiconductor research; [HSDB] May be present in wood preservatives and pesticides; Occurs in coal tar volatiles, tobacco smoke, exhaust emissions, charcoal broiled meat smoke, edible oils, surface waters, waste waters, and lake sediments; [CHEMINFO]Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
- Applying Wood Preservatives [Category: Other]Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
- Important source of dyestuffs (manufacturing anthraquinone, alizarin dyes).Hazardous Substances Data Bank (HSDB)
- PreservativeEPA Chemical Data Reporting (CDR)
Description
- Anthracene can cause cancer according to California Labor Code and the World Health Organization's International Agency for Research on Cancer (IARC).California Office of Environmental Health Hazard Assessment (OEHHA)
- Anthracene is a white to yellow solid with a weak aromatic odor. Sinks in water. (USCG, 1999)CAMEO Chemicals
- Acene is a polycyclic aromatic hydrocarbon consisting of fused benzene rings in a rectilinear arrangement. It is an ortho-fused polycyclic arene and a member of acenes.ChEBI
2Hazard identification
- Signal word
- Danger
- Pictograms
- GHS07, GHS08, GHS09
- Classification source
- European Chemicals Agency (ECHA)
Precautionary statements
| Code | Statement |
|---|---|
| P203 | Obtain, read and follow all safety instructions before use. |
| P264 | Wash hands [and ...] thoroughly after handling. |
| P264+P265 | Wash hands [and ...] thoroughly after handling. Do not touch eyes. |
| P273 | Avoid release to the environment. |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... |
| P302+P352 | IF ON SKIN: wash with plenty of water/... |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. |
| P318 | if exposed or concerned, get medical advice. |
| P321 | Specific treatment (see ... on this label). |
| P332+P317 | If skin irritation occurs: Get medical help. |
| P337+P317 | If eye irritation persists: Get medical help. |
| P362+P364 | Take off contaminated clothing and wash it before reuse. |
| P391 | Collect spillage. |
| P405 | Store locked up. |
| P501 | Dispose of contents/container to ... |
Other reported classifications
5 classification records exist across sources. Differences usually reflect purity, physical form or impurities.
| Source | Signal | Hazard codes |
|---|---|---|
| NITE-CMC | Danger | H317, H335, H350, H373 |
| NITE-CMC | Danger | H350 |
| NITE-CMC | Warning | H317, H319, H335, H351 |
| Hazardous Substances Data Bank (HSDB) | Warning | H315, H319, H335, H400, H410 |
NFPA 704 rating
- 1 - Materials that, under emergency conditions, can cause significant irritation.Hazardous Substances Data Bank (HSDB)
- 1 - Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.Hazardous Substances Data Bank (HSDB)
- 0 - Materials that in themselves are normally stable, even under fire conditions.Hazardous Substances Data Bank (HSDB)
Health hazards
- Inhalation of dust irritates nose and throat. Contact with eyes causes irritation. (USCG, 1999)CAMEO Chemicals
Fire hazards
- This chemical is combustible. (NTP, 1992)CAMEO Chemicals
- Combustible. Finely dispersed particles form explosive mixtures in air.ILO-WHO International Chemical Safety Cards (ICSCs)
Hazards summary
- A minor skin and respiratory tract irritant; [ICSC] Photosensitizing agent that may cause acute dermatitis; [HSDB] Minimal Risk Level (oral dose for 15-364 days) = 10 mg/kg/day (hepatic); [ATSDR] An irritant; May cause photosensitization; Effects in high-dose animal studies include fatty liver degeneration; [MSDSonline] See POLYCYCLIC AROMATIC HYDROCARBONS.Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
3Composition / information on ingredients
| Substance | CAS | EC | Formula |
|---|---|---|---|
| Anthracene | 120-12-7 | 204-371-1 | C14H10 |
This page describes the pure substance. Commercial products may be solutions or mixtures. Check Section 3 of your supplier's SDS for concentrations and other ingredients.
4First-aid measures
- EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.CAMEO Chemicals
Symptoms of exposure
- Cough. Sore throat.ILO-WHO International Chemical Safety Cards (ICSCs)
- Redness.ILO-WHO International Chemical Safety Cards (ICSCs)
- Redness. Pain.ILO-WHO International Chemical Safety Cards (ICSCs)
5Fire-fighting measures
- Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Hazardous Substances Data Bank (HSDB)
- Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.Hazardous Substances Data Bank (HSDB)
- To fight fire, use water, foam, carbon dioxide, water spray or mist, dry chemical.Hazardous Substances Data Bank (HSDB)
Hazardous combustion products
- Poisonous gases are produced in fire.Hazardous Substances Data Bank (HSDB)
6Accidental release measures
Spill cleanup
- Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: P2 filter respirator for harmful particles.ILO-WHO International Chemical Safety Cards (ICSCs)
- ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.Hazardous Substances Data Bank (HSDB)
- Evacuate persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Establish ventilation to keep levels below explosive limit. Collect powdered material in the most convenient and safe manner and deposit in sealed containers. Ventilate area after cleanup is complete. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters.Hazardous Substances Data Bank (HSDB)
7Handling and storage
- Separated from strong oxidants. Well closed.ILO-WHO International Chemical Safety Cards (ICSCs)
- Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non Combustible Solids.Hazardous Substances Data Bank (HSDB)
- Store in a secure poison location. ... Before entering a confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Anthracene must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine), chromic acid, and calcium hypochlorite, since violent reactions occur. Store in tightly closed containers in a cool, well-ventilated area. Sources of ignition, such as smoking and open flames, are prohibited where anthracene is used, handled, or stored in a manner that could create a potential fire or explosion hazard.Hazardous Substances Data Bank (HSDB)
8Exposure controls / personal protection
| Limit | Value | Source |
|---|---|---|
| OSHA PEL | 0.2 mg/m³ as Coal tar pitch volatiles (benzene soluble fraction) | Occupational Safety and Health Administration (OSHA) |
| NIOSH REL | 0.1 mg/m³ | Occupational Safety and Health Administration (OSHA) |
| ACGIH TLV | 8 Hr Time Weighted Avg (TWA): 0.2 mg/cu m. /Coal tar pitch volatiles, as benzene soluble aerosol/ | Hazardous Substances Data Bank (HSDB) |
| ACGIH TLV | Peak Exposure Recommendation: Transient increases in workers' exposure levels may exceed 3 times the value of the TLV-TWA level for no more than 15 minutes at a time, on no more than 4 occasions spaced 1 hour apart during a workday, and under no circumstances should they exceed 5 times the value of the TLV-TWA level. In addition, the 8-hour TWA is not to be exceeded for an 8-hour work period. /Coal tar pitch volatiles, as benzene soluble aerosol/ | Hazardous Substances Data Bank (HSDB) |
| IDLH | NIOSH considers coal tar pitch volatiles to be potential occupational carcinogens. /Coal tar pitch volatiles/ | Hazardous Substances Data Bank (HSDB) |
Personal protective equipment
- Dust mask; goggles or face shield; rubber gloves (USCG, 1999)CAMEO Chemicals
- Eye/face protection: Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Hazardous Substances Data Bank (HSDB)
- Skin protection: Handle with gloves.Hazardous Substances Data Bank (HSDB)
- Body Protection: Impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.Hazardous Substances Data Bank (HSDB)
9Physical and chemical properties
| Molecular weight | 178.23 g/mol |
|---|---|
| Physical description | Anthracene is a white to yellow solid with a weak aromatic odor. Sinks in water. (USCG, 1999) CAMEO Chemicals Other Solid EPA Chemical Data Reporting (CDR) |
| Color / form | Monoclinic plates from alcohol recrystallization; when pure, colorless with violet fluorescence Hazardous Substances Data Bank (HSDB) Tablets or monoclinic prisms from alcohol Hazardous Substances Data Bank (HSDB) |
| Odor | Weak aromatic odor Hazardous Substances Data Bank (HSDB) |
| Boiling point | 644 °F at 760 mmHg (corrected); 439.7 °F at 53 mmHg, sublimes (NTP, 1992) CAMEO Chemicals 341.3 °C Hazardous Substances Data Bank (HSDB) 342 °C ILO-WHO International Chemical Safety Cards (ICSCs) |
| Melting point | 421 to 424 °F (NTP, 1992) CAMEO Chemicals 216 °C Hazardous Substances Data Bank (HSDB) 218 °C ILO-WHO International Chemical Safety Cards (ICSCs) |
| Flash point | 250 °F (NTP, 1992) CAMEO Chemicals 121 °C Haz-Map, Information on Hazardous Chemicals and Occupational Diseases 121.0 °C (249.8 °F) - closed cup Hazardous Substances Data Bank (HSDB) |
| Autoignition temperature | 1004 °F (USCG, 1999) CAMEO Chemicals 540 °C (1004 °F) Hazardous Substances Data Bank (HSDB) |
| Density / specific gravity | 1.24 at 68 °F (USCG, 1999) - Denser than water; will sink CAMEO Chemicals 1.25 at 27 °C/4 °C Hazardous Substances Data Bank (HSDB) |
| Vapor density | 6.15 (NTP, 1992) - Heavier than air; will sink (Relative to Air) CAMEO Chemicals 6.15 (Air = 1.0) Hazardous Substances Data Bank (HSDB) |
| Vapor pressure | 1 mmHg at 293 °F (sublimes) (NTP, 1992) CAMEO Chemicals 0.00000267 [mmHg] Haz-Map, Information on Hazardous Chemicals and Occupational Diseases |
| Solubility | less than 1 mg/mL at 68 °F (NTP, 1992) CAMEO Chemicals In water, 4.34X10-2 mg/L at 24 °C Hazardous Substances Data Bank (HSDB) Insoluble in water Hazardous Substances Data Bank (HSDB) |
| log Kow (LogP) | log Kow = 4.45 Hazardous Substances Data Bank (HSDB) 4.5 (calculated) ILO-WHO International Chemical Safety Cards (ICSCs) |
| Decomposition | Hazardous decomposition products formed under fire conditions - Carbon oxides. Hazardous Substances Data Bank (HSDB) |
| Explosive / flammable limits | 0.6 % (NTP, 1992) CAMEO Chemicals 0.6% Occupational Safety and Health Administration (OSHA) Lower flammable limit: 0.6% by volume; /No upper limit available/ Hazardous Substances Data Bank (HSDB) |
10Stability and reactivity
Reactivity
- ANTHRACENE will spontaneously burst into flame on contact with chromic acid, and other strong oxidants.CAMEO Chemicals
- Flammable. Insoluble in water.CAMEO Chemicals
Incompatible materials and hazardous reactions
- Incompatible materials: Strong oxidizing agents, hypochlorites.Hazardous Substances Data Bank (HSDB)
- Anthracene will burst into flame on contact with chromic acid.Hazardous Substances Data Bank (HSDB)
- Anthracene heats on contact with calcium hypochlorite.Hazardous Substances Data Bank (HSDB)
Chemical stability
- Stable under recommended storage conditions.Hazardous Substances Data Bank (HSDB)
11Toxicological information
Short-term exposure effects
- The substance is mildly irritating to the skin and respiratory tract.ILO-WHO International Chemical Safety Cards (ICSCs)
Long-term exposure effects
- Repeated or prolonged contact with skin may cause dermatitis under the influence of UV light.ILO-WHO International Chemical Safety Cards (ICSCs)
12Ecological information
Not available in the public sources we compile. Check Section 12 of the supplier's SDS.
13Disposal considerations
- SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.Hazardous Substances Data Bank (HSDB)
- SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal.Hazardous Substances Data Bank (HSDB)
- Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber; Contaminated packaging: Dispose of as unused product.Hazardous Substances Data Bank (HSDB)
14Transport information
Not available in the public sources we compile. Check Section 14 of the supplier's SDS.
15Regulatory information
- Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Polynuclear aromatic hydrocarbons (including benzanthracenes, benzopyrenes, benzofluoranthene, chrysenes, dibenz-anthracenes, and indenopyrenes)/Hazardous Substances Data Bank (HSDB)
- For the maximum protection of human health from the potential carcinogenic effects of exposure to polynuclear aromatic hydrocarbons through ingestion of contaminated water and contaminated aquatic organisms, the ambient water concentration should be zero, based on the nonthreshold assumption for this chemical. However, zero level may not be attainable at the present time. Therefore, the levels which may result in incremental increase of cancer risk over the lifetime are estimated at 1X10-5, 1X10-6, and 1X10-7. The corresponding recommended criteria are 28.0 ng/L, 2.8 ng/L, and 0.28 ng/L, respectively.Hazardous Substances Data Bank (HSDB)
- Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 5000 lb or 2270 kg. The toll free number of the NRC is (800) 424-8802. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).Hazardous Substances Data Bank (HSDB)
- Pursuant to section 8(d) of TSCA, EPA promulgated a model Health and Safety Data Reporting Rule. The section 8(d) model rule requires manufacturers, importers, and processors of listed chemical substances and mixtures to submit to EPA copies and lists of unpublished health and safety studies. Anthracene is included on this list. Effective date 6/1/87; Sunset date: 6/1/97.Hazardous Substances Data Bank (HSDB)
Overview of SDS regulations (OSHA HazCom, WHMIS, REACH/CLP) →
16Other information
Compiled from PubChem CID 8418 and the sources it aggregates (attributed inline). Data retrieved 2026-10-12. This summary describes the pure substance and is not a supplier SDS.
Frequently asked questions about Anthracene
What is the CAS number for Anthracene?
The CAS Registry Number for Anthracene is 120-12-7. Its EC (EINECS) number is 204-371-1.
Is Anthracene hazardous?
Yes. Anthracene is classified under GHS with the signal word “Danger”. Hazard statements: H315: Causes skin irritation; H319: Causes serious eye irritation; H350: May cause cancer; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects.
Is Anthracene flammable?
Anthracene is not classified as flammable under its primary GHS classification, but a flash point of 250 °F (NTP, 1992) has been reported, so it can burn under some conditions.
Which GHS pictograms apply to Anthracene?
Anthracene labels carry GHS07 (Exclamation Mark), GHS08 (Health Hazard), and GHS09 (Environment).
What are the workplace exposure limits for Anthracene?
OSHA PEL: 0.2 mg/m³ as Coal tar pitch volatiles (benzene soluble fraction). NIOSH REL: 0.1 mg/m³. ACGIH TLV: 8 Hr Time Weighted Avg (TWA): 0.2 mg/cu m. /Coal tar pitch volatiles, as benzene soluble aerosol/. IDLH: NIOSH considers coal tar pitch volatiles to be potential occupational carcinogens. /Coal tar pitch volatiles/.
What PPE is needed when handling Anthracene?
Dust mask; goggles or face shield; rubber gloves (USCG, 1999)
What is the first aid for Anthracene exposure?
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
How should Anthracene be stored?
Separated from strong oxidants. Well closed.